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Royal Society of Chemistry, Chemical Communications, 32(49), p. 3312, 2013

DOI: 10.1039/c3cc41173g

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Remarkable cage deboronation and rearrangement of a closo-1,12-dicarbadodecaborane to form a neutral nido-7,9-dicarbaundecaborane.

Journal article published in 2013 by Joseph A. Ioppolo, Mohan Bhadbhade, Mark A. Fox ORCID, Louis M. Rendina
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Deboronation and cage rearrangement of the closo-1,12-carborane salt [1,12-(PPh2Me)2-1,12-C2B10H10]I2 occurs in refluxing methanol to give the zwitterionic nido-7,9-carborane 7,9-(PPh2Me)2-7,9-C2B9H9. Notably, deboronation and cage substitution of the isomeric closo-1,7-carborane salt [1,7-(PPh2Me)2-1,7-C2B10H10]I2 takes place in methanol to afford the salt [10-OMe-7,9-(PPh2Me)2-7,9-C2B9H9]I.