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Royal Society of Chemistry, Chemical Communications, 84(48), p. 10413, 2012

DOI: 10.1039/c2cc35623f

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Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II).

Journal article published in 2012 by Luke Tuxworth, Lise Baiget, Andreas Phanopoulos, Owen J. Metters, Andrei S. Batsanov, Mark A. Fox ORCID, Judith A. K. Howard, Philip W. Dyer
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This paper is available in a repository.

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Abstract

N-Diphenylphosphino-7-aza-benzobicyclo[2.2.1]hept-2-ene (2) behaves as a chelating phosphine-alkene ligand for Pd(0) and Pd(II), promoting direct alkyl-alkyl and indirect alkyl-halide reductive elimination reactions due to the stabilisation of the resulting bis(phosphine-alkene)Pd(0) complex.