Published in
Royal Society of Chemistry, Energy & Environmental Science, 23(17), p. 9134-9143, 2024
DOI: 10.1039/d4ee03058c
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Benign methylformamidinium byproduct induced by cation heterogeneity inhibits local formation of δ-phase perovskites
Journal article published in 2024 by
Jihoo Lim,
Jaehui Kim,
Josh Davies-Jones 
,
Mohsen Danaie ,
Eunyoung Choi ,
Hongjae Shim,
Liang Chen,
Jincheol Kim ,
Judy S. Kim ,
Philip R. Davies ,
Jan Seidel ,
Martin A. Green,
Samuel D. Stranks ,
Sang Il Seok ,
Jae Sung Yun
,
Mohsen Danaie ,
Eunyoung Choi ,
Hongjae Shim,
Liang Chen,
Jincheol Kim ,
Judy S. Kim ,
Philip R. Davies ,
Jan Seidel ,
Martin A. Green,
Samuel D. Stranks ,
Sang Il Seok ,
Jae Sung Yun
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Abstract
Methylammonium chloride (MACl) selectively promotes the formation of N-methylformamidinium (MFA+)PbI3 at grain boundaries (GBs) and as clusters near GBs while suppress the formation of δ-FAPbI3.