Published in
Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 13(12), p. 7605-7621, 2024
DOI: 10.1039/d3ta07391b
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Uncovering the critical function of lanthanum in CH<sub>4</sub> production from CO<sub>2</sub> using exsolved LaNiO<sub>3</sub> perovskite catalysts
Journal article published in 2024 by
Mathias Barreau,
Davide Salusso,
Jinming Zhang,
Michael Haevecker,
Detre Teschner,
Anna Efimenko,
Fabrice Bournel,
Jean-Jacques Gallet,
Elisa Borfecchia 
,
Kamil Sobczak,
Corinne Petit,
Spyridon Zafeiratos
,
Kamil Sobczak,
Corinne Petit,
Spyridon Zafeiratos
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Abstract
The exsolved LaNiO3 perovskite catalyst exhibits superior performance compared to supported Ni/La2O3 attributed to the critical La–Ni arrangement differences, including Ni encapsulation and lanthana's affinity for hydroxide/carbonate formation.