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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 36(25), p. 24853-24861, 2023

DOI: 10.1039/d3cp02509h

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Mimicking the C<sub>2</sub> molecule: M<sub>2</sub>B<sub>2</sub> and M<sub>3</sub>B<sub>2</sub><sup>+</sup> clusters (M = Li, Na) and the reactivity of the N-heterocyclic carbene bound Li<sub>2</sub>B<sub>2</sub> complex

Journal article published in 2023 by Yu-Qian Liu, Gai-Ru Yan, Li-Juan Cui ORCID, Bing Yan ORCID, Sudip Pan ORCID, Zhong-Hua Cui ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The covalent bonding pattern in B2M2 and B2M3+ mimics C2 molecule. The viability of ligand-stabilized L–B2Li2–L (L = NHC, PPh3) complexes is studied. Li2B2(NHC)2 can activate CO and CO2 to a larger extent than B2(NHC)2.