Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 36(25), p. 24853-24861, 2023
DOI: 10.1039/d3cp02509h
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Mimicking the C<sub>2</sub> molecule: M<sub>2</sub>B<sub>2</sub> and M<sub>3</sub>B<sub>2</sub><sup>+</sup> clusters (M = Li, Na) and the reactivity of the N-heterocyclic carbene bound Li<sub>2</sub>B<sub>2</sub> complex
Journal article published in 2023 by
Yu-Qian Liu,
Gai-Ru Yan,
Li-Juan Cui 
,
Bing Yan ,
Sudip Pan ,
Zhong-Hua Cui
,
Bing Yan ,
Sudip Pan ,
Zhong-Hua Cui
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Abstract
The covalent bonding pattern in B2M2 and B2M3+ mimics C2 molecule. The viability of ligand-stabilized L–B2Li2–L (L = NHC, PPh3) complexes is studied. Li2B2(NHC)2 can activate CO and CO2 to a larger extent than B2(NHC)2.