Published in
Royal Society of Chemistry, Inorganic Chemistry Frontiers, 14(10), p. 4197-4208, 2023
DOI: 10.1039/d3qi00290j
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Strong magnetic exchange coupling in Ln<sub>2</sub> metallocenes attained by the trans-coordination of a tetrazinyl radical ligand
Journal article published in 2023 by
Niki Mavragani 
,
Alexandros A. Kitos ,
Jakub Hrubý,
Stephen Hill ,
Akseli Mansikkamäki ,
Jani O. Moilanen ,
Muralee Murugesu
,
Alexandros A. Kitos ,
Jakub Hrubý,
Stephen Hill ,
Akseli Mansikkamäki ,
Jani O. Moilanen ,
Muralee Murugesu
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Abstract
One of the strongest Ln-rad magnetic coupling was attained in a family of dinuclear Ln metallocenes via the trans coordination mode of a tetrazinyl-based radical bridge, with the Tb(iii) and Dy(iii) analogues exhibiting SMM behaviour.