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Royal Society of Chemistry, Dalton Transactions, 25(52), p. 8676-8684, 2023

DOI: 10.1039/d3dt01276j

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The elusive active species in nickel(ii)-mediated oxidations of hydrocarbons by peracids: a Ni<sup>II</sup>–oxyl species, an aroyloxy radical, or a Ni<sup>II</sup>–peracid complex?

Journal article published in 2023 by Zhimin Wu, Dongru Sun ORCID, Yong-Min Lee ORCID, Yufen Zhao ORCID, Wonwoo Nam ORCID, Yong Wang ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A multiple-oxidant mechanism, in which a mCBA· radical, a NiIII–OH species and a NiII–mCPBA complex act as the oxdiants, works in Ni(ii)-mediated oxidation of cyclohexane with mCPBA.