Published in
Royal Society of Chemistry, New Journal of Chemistry, 22(48), p. 10002-10009, 2024
DOI: 10.1039/d4nj01402b
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Monomers and dimers of fullerenes in the radical anion salts with dyes, (astrophloxine<sup>+</sup>)<sub>2</sub>(C<sub>60</sub>˙<sup>−</sup>)<sub>2</sub> and (astrophloxine<sup>+</sup>)<sub>2</sub>(C<sub>70</sub><sup>−</sup>)<sub>2</sub>: suppression of the C<sub>60</sub>˙<sup>−</sup> dimerization by π-stacking
Journal article published in 2024 by
Pavel A. Sobov,
Maxim A. Faraonov 
,
Salavat S. Khasanov,
Akihiro Otsuka ,
Hideki Yamochi ,
Hiroshi Kitagawa ,
Dmitri V. Konarev
,
Salavat S. Khasanov,
Akihiro Otsuka ,
Hideki Yamochi ,
Hiroshi Kitagawa ,
Dmitri V. Konarev
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Abstract
Radical anion salts (astrophloxine+)2(C60·-)2×C6H4Cl2×C6H14 (1) and (astrophloxine+)2(C70−)2 (2) have been obtained with cationic dye. Singly bonded (C60−)2 dimers are partially formed in 1, whereas singly bonded (C70−)2 dimers are found in 2.