Royal Society of Chemistry, Journal of Materials Chemistry, 40(21), p. 16257
DOI: 10.1039/c1jm13628c
Full text: Download
We report the preparation of a 4,4′-bis(2-ethylhexyl)dithieno[3,2-b:2′,3′-d]germole monomer and its polymerisation with 2,1,3-benzothiadiazole. Unlike the analogous dithienosilole, the dithienogermole is sufficiently stable under basic conditions to enable Suzuki polycondensation. The resulting high molecular weight polymer exhibits a high propensity to order in the solid state and demonstrates charge carrier mobilities up to 0.11 cm2 V−1 s−1 in field effect transistors. A PGeBTBT based BHJ solar cell device achieved a PCE of 4.5% with a high Jsc of 18.6 mA cm−2.