Published in
Royal Society of Chemistry, Chemical Communications, 50(59), p. 7803-7806, 2023
DOI: 10.1039/d3cc01831h
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A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker
Journal article published in 2023 by
Borja Ortín-Rubio 
,
Cristina Perona-Bermejo ,
José A. Suárez del Pino,
Francisco J. Carmona ,
Felipe Gándara ,
Jorge A. R. Navarro ,
Judith Juanhuix ,
Inhar Imaz,
Daniel Maspoch
,
Cristina Perona-Bermejo ,
José A. Suárez del Pino,
Francisco J. Carmona ,
Felipe Gándara ,
Jorge A. R. Navarro ,
Judith Juanhuix ,
Inhar Imaz,
Daniel Maspoch
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Abstract
We present BCN-348, a new high-connected MOF built from an 8-c cubic Zr-oxocluster and an 8-c organic linker. BCN-348 shows a 3,4,8-c eps net, mesoporosity, hydrolytic stability, and acts as a catalyst for hydrolysis of a nerve-agent simulant.