Published in
Royal Society of Chemistry, Chemical Communications, 97(59), p. 14407-14410, 2023
DOI: 10.1039/d3cc04168a
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Tracking nitrite's deviation from Stokes–Einstein predictions with pulsed field gradient <sup>15</sup>N NMR spectroscopy
Journal article published in 2023 by
Trent R. Graham 
,
Yihui Wei,
Eric D. Walter ,
Emily T. Nienhuis ,
Jaehun Chun ,
Gregory K. Schenter ,
Kevin M. Rosso ,
Carolyn I. Pearce ,
Aurora E. Clark
,
Yihui Wei,
Eric D. Walter ,
Emily T. Nienhuis ,
Jaehun Chun ,
Gregory K. Schenter ,
Kevin M. Rosso ,
Carolyn I. Pearce ,
Aurora E. Clark
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Abstract
The diffusivities of nitrite in concentrated sodium nitrite and simulant radioactive waste observed with 15N PFGSTE-NMR spectroscopy exceeded predictions based on the Stokes–Einstein relationship.