Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 43(25), p. 29566-29575, 2023
DOI: 10.1039/d3cp04561g
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High-concentration LiPF<sub>6</sub>/sulfone electrolytes: structure, transport properties, and battery application
Journal article published in 2023 by
Yosuke Ugata 
,
Yichuan Chen,
Shuhei Miyazaki,
Shohei Sasagawa,
Kazuhide Ueno ,
Masayoshi Watanabe ,
Kaoru Dokko
,
Yichuan Chen,
Shuhei Miyazaki,
Shohei Sasagawa,
Kazuhide Ueno ,
Masayoshi Watanabe ,
Kaoru Dokko
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Abstract
LiPF6 and sulfolane form a stable crystalline solvate at a 1 : 4 molar ratio; however, the partial substitution of sulfolane with another sulfone suppresses solvate crystallization, enabling its use as a liquid electrolyte in Li batteries.