Published in
Royal Society of Chemistry, Organic Chemistry Frontiers, 19(10), p. 4732-4739, 2023
DOI: 10.1039/d3qo00700f
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Ir–Na cooperativity controls the diastereoselectivity of borrowing hydrogen C–C alkylation on isosorbide: synthesis methodology and mechanistic investigation
Journal article published in 2023 by
Jordan François 
,
Jordan Rio,
Erwann Jeanneau,
Marie-Ève L. Perrin ,
Maïwenn Jacolot ,
Pierre-Adrien Payard ,
Florence Popowycz
,
Jordan Rio,
Erwann Jeanneau,
Marie-Ève L. Perrin ,
Maïwenn Jacolot ,
Pierre-Adrien Payard ,
Florence Popowycz
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Abstract
The C–C alkylation of isosorbide derivative was achieved with excellent diastereocontrol using an Ir-based organometallic homogeneous catalyst.