Published in
Royal Society of Chemistry, Inorganic Chemistry Frontiers, 11(8), p. 2809-2816, 2021
DOI: 10.1039/d1qi00309g
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A ferroelastic molecular rotor crystal showing inverse temperature symmetry breaking
Journal article published in 2021 by
Le-Ping Miao 
,
Lin Chu,
Xiang-Bin Han ,
Bei-Dou Liang,
Chao-Yang Chai,
Chang-Chun Fan ,
Xiao-Xu Wang ,
Ye-Feng Yao ,
Wen Zhang
,
Lin Chu,
Xiang-Bin Han ,
Bei-Dou Liang,
Chao-Yang Chai,
Chang-Chun Fan ,
Xiao-Xu Wang ,
Ye-Feng Yao ,
Wen Zhang
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Abstract
A molecular rotor crystal shows a ferroelastic phase transition with unique inverse temperature symmetry breaking which is a result of concerted molecular movement triggered by anisotropic steric repulsion among adjacent molecules.