Published in
Royal Society of Chemistry, CrystEngComm, 23(23), p. 4136-4142, 2021
DOI: 10.1039/d1ce00301a
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DCM self-trapping by the host deformation in flexible host–guest molecules
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Abstract
The desolvated structure can self-trap the DCM molecules to return to the 1·DCM state via ligand deformation even under weak host–guest interactions. The capture behavior of DCM is mostly due to the flexibility of the ligand.