Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 20(23), p. 11990-12004, 2021
DOI: 10.1039/d1cp00839k
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Modelling the non-local thermodynamic equilibrium spectra of silylene (SiH<sub>2</sub>)
Journal article published in 2021 by
Victoria H. J. Clark 
,
Sergei N. Yurchenko
,
Sergei N. Yurchenko
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Abstract
Vibrational populations of molecules produced in reactions can be very different from the Boltzmann distribution. These so-called non-LTE populations encode information about the structural reaction dynamics and can manifest in the molecular spectra.