Published in
Royal Society of Chemistry, Catalysis Science & Technology, 17(11), p. 5802-5815, 2021
DOI: 10.1039/d1cy00421b
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Formation, dynamics, and long-term stability of Mn- and Fe-promoted Rh/SiO<sub>2</sub> catalysts in CO hydrogenation
Journal article published in 2021 by
Phil Preikschas 
,
Julia Bauer,
Kristian Knemeyer ,
Raoul Naumann d'Alnoncourt ,
Ralph Kraehnert ,
Frank Rosowski
,
Julia Bauer,
Kristian Knemeyer ,
Raoul Naumann d'Alnoncourt ,
Ralph Kraehnert ,
Frank Rosowski
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Abstract
Fe servers as an electronic modifier on Rh/SiO2 through in situ RhFe nanoalloy formation, whereas Mn is more likely a structural modifier and does not substantially change Rh's intrinsic product spectrum.