Published in
Royal Society of Chemistry, Organic Chemistry Frontiers, 18(8), p. 5058-5063, 2021
DOI: 10.1039/d1qo00782c
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Unveiling the abnormal effect of temperature on enantioselectivity in the palladium-mediated decabonylative alkylation of MBH acetate
Journal article published in 2021 by
Xian-Zhou Zheng,
Kai Chen 
,
Jun-An Xiao,
Jun Li,
Sha Wang,
Qing-Lan Zhao,
Hao-Yue Xiang,
Xiao-Qing Chen,
Hua Yang
,
Jun-An Xiao,
Jun Li,
Sha Wang,
Qing-Lan Zhao,
Hao-Yue Xiang,
Xiao-Qing Chen,
Hua Yang
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Abstract
An unusual temperature–enantioselectivity relationship was observed in the newly developed palladium-catalysed enantioselective nucleophilic substitution of cyclic Morita–Baylis–Hillman acetate and 4,4,4-trifluoro-1-phenyl-1,3-butanedione.