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Royal Society of Chemistry, Polymer Chemistry, 1(4), p. 166-173

DOI: 10.1039/c2py20656k

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Synthesis of block polymer miktobrushes

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Well defined mu-A(BC)(n) 'miktobrush' terpolymers were synthesized utilizing the alternating radical copolymerization of two hydrophobic and incompatible macromonomer (MM) building blocks; a maleimide (MI) end functionalized poly(methyl-caprolactone) block (MI-PMCL) or 'C' and a styrene (Sty) end functionalized poly(perfluoro propylene oxide) block (Sty-PFPO) or 'F'. Polymerizations were mediated by a poly(ethylene oxide) (PEO) functionalized reversible addition-fragmentation chain transfer (RAFT) agent (PEO-CTA) or 'O' to control the chain growth of the MMs from the O block to form O(CF)(n) ; 나노과학기술대학원