Published in
Royal Society of Chemistry, Dalton Transactions, 36(50), p. 12430-12434, 2021
DOI: 10.1039/d1dt02268g
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Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations
Journal article published in 2021 by
Walace D. do Pim 
,
Ingrid F. Silva ,
Eufrânio N. da Silva Júnior ,
Humberto O. Stumpf ,
Willian X. C. Oliveira ,
Emerson F. Pedroso ,
Carlos B. Pinheiro ,
Yves Journaux ,
Felipe Fantuzzi ,
Ivo Krummenacher ,
Holger Braunschweig ,
Bernd Engels ,
Joan Cano ,
Miguel Julve ,
Cynthia L. M. Pereira
,
Ingrid F. Silva ,
Eufrânio N. da Silva Júnior ,
Humberto O. Stumpf ,
Willian X. C. Oliveira ,
Emerson F. Pedroso ,
Carlos B. Pinheiro ,
Yves Journaux ,
Felipe Fantuzzi ,
Ivo Krummenacher ,
Holger Braunschweig ,
Bernd Engels ,
Joan Cano ,
Miguel Julve ,
Cynthia L. M. Pereira
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Abstract
An unexpected heterobimetallic ring {CoII6CuII6} was synthesised by slow diffusion in water under ambient conditions and its dc magnetic properties were analysed through an effective Hamiltonian in the light of DFT type calculations.