Published in
Royal Society of Chemistry, Organic Chemistry Frontiers, 21(8), p. 6009-6018, 2021
DOI: 10.1039/d1qo00942g
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A palladium/Et<sub>3</sub>N·HI-catalyzed highly selective 7-endo alkyl-Heck-type reaction of epoxides and a DFT study on the mechanism
Journal article published in 2021 by
Xu Dong 
,
Li-Ping Xu ,
Yi Yang,
Yunxia Liu,
Xin Li,
Qing Liu,
Liang Zheng,
Fagang Wang,
Hui Liu
,
Li-Ping Xu ,
Yi Yang,
Yunxia Liu,
Xin Li,
Qing Liu,
Liang Zheng,
Fagang Wang,
Hui Liu
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Abstract
A highly efficient 7-endo alkyl-Heck reaction was achieved via palladium catalyzed ring-opening of epoxides, providing a variety of 6-aryl-2,3,4,7-tetrahydro-1H-azepin-3-ols and 6-aryl-2,3,4,5-tetrahydrooxepin-3-ols.