Published in
Royal Society of Chemistry, Inorganic Chemistry Frontiers, 22(8), p. 4806-4819, 2021
DOI: 10.1039/d1qi00904d
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Optimizing the relaxivity at high fields: systematic variation of the rotational dynamics in polynuclear Gd-complexes based on the AAZTA ligand
Journal article published in 2021 by
Lorenzo Tei 
,
Giuseppe Gugliotta,
Davide Marchi,
Maurizio Cossi ,
Simonetta Geninatti Crich ,
Mauro Botta
,
Giuseppe Gugliotta,
Davide Marchi,
Maurizio Cossi ,
Simonetta Geninatti Crich ,
Mauro Botta
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Abstract
A homogeneous series of polynuclear Gd-complexes (n = 1–8) based on a stable and bis-hydrated [Gd(AAZTA)]− chelate shows high relaxivity values at high fields (1.5–7 T), per Gd, particularly pronounced for the more rigid and compact members.