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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 42(23), p. 24140-24153, 2021

DOI: 10.1039/d1cp02921e

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Valence-shell photoelectron circular dichroism of ruthenium(iii)-tris-(acetylacetonato) gas-phase enantiomers

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Mirror-image VUV photoelectron circular dichroism spectra (PECD) of the propeller-type chiral Ru(acac)3 enantiomers were measured with asymmetries up to 14%, suggesting that PECD is a universal mechanism, inherent to any type of chirality.