Published in
Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 41(9), p. 23459-23466, 2021
DOI: 10.1039/d1ta06716h
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Exemption of lattice collapse in Ni–MnO<sub>2</sub> birnessite regulated by the structural water mobility
Journal article published in 2021 by
Xiaoqiang Shan 
,
Ranga Teja Pidathala ,
SaeWon Kim,
Wenqian Xu,
Milinda Abeykoon ,
Gihan Kwon ,
Daniel Olds,
Badri Narayanan ,
Xiaowei Teng
,
Ranga Teja Pidathala ,
SaeWon Kim,
Wenqian Xu,
Milinda Abeykoon ,
Gihan Kwon ,
Daniel Olds,
Badri Narayanan ,
Xiaowei Teng
This paper is made freely available by the publisher.
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Abstract
The lattice collapse occurs in MnO2 birnessite at high voltage due to the structural water motion, which is exempted in Ni-doped MnO2 due to a significant decrease in electrostatic repulsion between lattice oxygens.