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Royal Society of Chemistry, Green Chemistry, 22(23), p. 8995-9013, 2021

DOI: 10.1039/d1gc03022a

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Incorporation of catechyl monomers into lignins: lignification from the non-phenolic endviaDiels–Alder cycloaddition?

Journal article published in 2021 by Daisuke Ando ORCID, Fachuang Lu ORCID, Hoon Kim ORCID, Alexis Eugene ORCID, Yuki Tobimatsu ORCID, Ruben Vanholme ORCID, Thomas J. Elder ORCID, Wout Boerjan ORCID, John Ralph ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Catechyl monomers 1-electron-oxidize and undergo radical coupling to produce benzodioxane units in lignin. Derived o-quinones undergo Diels–Alder reactions giving oxatricyclo and new benzodioxane products, but does this occur in lignification?.