Published in
Royal Society of Chemistry, Dalton Transactions, 46(50), p. 17086-17100, 2021
DOI: 10.1039/d1dt03122h
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Nickel(ii) monobenzoporphyrins and chlorins: synthesis, electrochemistry and anion sensing properties
Journal article published in 2021 by
Sandeep Kumar,
Nivedita Chaudhri 
,
W. Ryan Osterloh ,
Karl M. Kadish ,
Muniappan Sankar
,
W. Ryan Osterloh ,
Karl M. Kadish ,
Muniappan Sankar
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Abstract
New NiII monobenzoporphyrins and chlorins were synthesized. One compound was used as a chemodosimeter for naked-eye detection of cyanide in nonaqueous media giving a new π-extended porphyrin product with NIR absorptions and a 1.47 V HOMO–LUMO gap.