Published in
Royal Society of Chemistry, Chemical Communications, 28(46), p. 5106
DOI: 10.1039/c0cc00485e
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A new family of oxime-based hexanuclear manganese(iii) single molecule magnets with high anisotropy energy barriers
Journal article published in 2010 by
Adrian-Raul Tomsa,
José Martínez-Lillo,
Yanling Li,
Lise-Marie Chamoreau,
Kamal Boubekeur,
Fernanda Farias,
Miguel A. Novak,
Eduard Cremades,
Eliseo Ruiz 
,
Anna Proust ,
Michel Verdaguer,
Pierre Gouzerh
,
Anna Proust ,
Michel Verdaguer,
Pierre Gouzerh
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Abstract
A magneto-structural study of two salicylamidoxime-based {Mn(6)} single-molecule magnets revealed that their anisotropy energy barriers, which can reach the current record for d-transition metal complexes, are strongly dependent upon the precise arrangement of ligands and the solvation state.