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Royal Society of Chemistry, Chemical Communications, 7(58), p. 997-1000, 2022

DOI: 10.1039/d1cc05904a

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2.2.2-Cryptand complexes of neptunium(iii) and plutonium(iii)

Journal article published in 2022 by Conrad A. P. Goodwin ORCID, Sierra R. Ciccone ORCID, Samuel Bekoe ORCID, Sourav Majumdar ORCID, Brian L. Scott ORCID, Joseph W. Ziller ORCID, Andrew J. Gaunt ORCID, Filipp Furche ORCID, William J. Evans ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The THF-soluble [An(crypt)(OTf)2][OTf] complexes for An = Np and Pu were synthesized from AnI3(THF)4 starting materials based on pilot studies of the An = U system. 5f3 U(iii), 5f4 Np(iii), and 5f5 Pu(iii) electron configurations are indicated by DFT analysis of their UV-visible-NIR spectra.