Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 7(24), p. 4196-4203, 2022
DOI: 10.1039/d1cp05371j
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Molecular insight into the role of zeolite lattice constraints on methane activation over the Cu–O–Cu active site
Journal article published in 2022 by
Muhammad Haris Mahyuddin 
,
Adhitya Gandaryus Saputro ,
Reza Pamungkas Putra Sukanli,
Fadjar Fathurrahman,
Jenny Rizkiana,
Ahmad Nuruddin,
Hermawan Kresno Dipojono
,
Adhitya Gandaryus Saputro ,
Reza Pamungkas Putra Sukanli,
Fadjar Fathurrahman,
Jenny Rizkiana,
Ahmad Nuruddin,
Hermawan Kresno Dipojono
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Abstract
The zeolite ring structure constrains the Cu–μO–Cu geometry and determines how the Cu–μO–Cu bonds weaken to allow a μO–H bond to form during the H–CH3 bond cleavage. The weaker the Cu–μO–Cu bonds, the stronger the μO–H bond.