Published in
Royal Society of Chemistry, Faraday Discussions, (234), p. 195-213, 2022
DOI: 10.1039/d1fd00094b
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Binding of the substrate analog methanol in the oxygen-evolving complex of photosystem II in the D1-N87A genetic variant of cyanobacteria
Journal article published in 2022 by
Vidmantas Kalendra,
Krystle M. Reiss,
Gourab Banerjee,
Ipsita Ghosh,
Amgalanbaatar Baldansuren,
Victor S. Batista,
Gary W. Brudvig 
,
K. V. Lakshmi
,
K. V. Lakshmi
This paper is made freely available by the publisher.
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Abstract
Two-dimensional 13C HYSCORE spectroscopy, in conjunction with QM/MM and DFT, indicates that methanol binds to the Mn4Ca-oxo cluster in the S2 state of D1-N87A photosystem II from Synechocystis sp. PCC 6803.