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Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 13(10), p. 7155-7164, 2022

DOI: 10.1039/d1ta09846b

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Investigating dry room compatibility of sulfide solid-state electrolytes for scalable manufacturing

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

When exposed to moisture, Li6PS5Cl undergoes both hydrolysis and hydration reactions. It can be partially recovered by heat treatment, but hydrolysis causes the formation of LiCl, Li2S, Li3PO4, and oxysulfides due to the irreversible sulfur loss.