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Royal Society of Chemistry, Organic and Biomolecular Chemistry, 30(20), p. 6019-6026, 2022

DOI: 10.1039/d2ob00391k

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Mechanistic investigation of enolate/stabilized vinylogous carbanion-mediated organocatalytic azide (3 + 2) cycloaddition reactions for the synthesis of 1,2,3-triazoles

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Studies of two organocatalyzed 1,3-dipolar cycloadditions are provided, with investigation of the elementary steps, intermediates, and transition states in terms of DFT calculations, supported by 1H NMR monitoring, along with DIAS analysis.