Published in
Royal Society of Chemistry, Organic Chemistry Frontiers, 10(9), p. 2797-2807, 2022
DOI: 10.1039/d2qo00241h
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Resolution of aryl-H-phosphinates applied in the synthesis of P-stereogenic compounds including a Brønsted acid NMR solvating agent
Journal article published in 2022 by
Bence Varga 
,
Daniella Vincze,
Hajnalka Pető,
Levente Buna,
János Pauló,
Tamás Holczbauer ,
Béla Mátravölgyi,
László Hegedűs ,
Elemér Fogassy ,
György Keglevich,
Péter Bagi
,
Daniella Vincze,
Hajnalka Pető,
Levente Buna,
János Pauló,
Tamás Holczbauer ,
Béla Mátravölgyi,
László Hegedűs ,
Elemér Fogassy ,
György Keglevich,
Péter Bagi
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Abstract
An enantioseparation method for the preparation of P-stereogenic H-phosphinates was elaborated. In stereoselective reactions, various chiral P-stereogenic compounds were prepared and their applications as chiral NMR solvating agents were assessed.