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Royal Society of Chemistry, Dalton Transactions, 25(51), p. 9596-9600, 2022

DOI: 10.1039/d2dt01371a

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Co-existence of five- and six-coordinate iron(ii) species captured in a geometrically strained spin-crossover Hofmann framework

Journal article published in 2022 by Luonan Xu, Zixi Xie ORCID, Katrina A. Zenere ORCID, Jack K. Clegg ORCID, Elise Kenny ORCID, Nicole J. Rijs, Guy N. L. Jameson ORCID, Cameron J. Kepert, Benjamin J. Powell, Suzanne M. Neville ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The use of an angular ligand drives the formation of an irregular Hofmann framework whereby 6-coordinate and rare 5-coordinate FeII species co-exist – the 6-coordinate species show a spin-crossover transition.