Published in
Royal Society of Chemistry, Chemical Communications, 61(58), p. 8532-8535, 2022
DOI: 10.1039/d2cc02969c
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Triple bonding between beryllium and nitrogen in HNBeCO
Journal article published in 2022 by
Lina Wang,
Sudip Pan 
,
Guanjun Wang ,
Xiaoqing Zeng ,
Mingfei Zhou ,
Gernot Frenking
,
Guanjun Wang ,
Xiaoqing Zeng ,
Mingfei Zhou ,
Gernot Frenking
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Abstract
HNBeCO is generated in a neon matrix and identified via vibrational spectroscopy. It possesses an unprecedented triple bond, consisting of two π-bonds and a dative σ-bond, with the former bonds being much stronger than the latter bond.