Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 36(24), p. 21645-21654, 2022
DOI: 10.1039/d2cp00749e
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Assessing the hydrotropic effect in the presence of electrolytes: competition between solute salting-out and salt-induced hydrotrope aggregation
Journal article published in 2022 by
Afonso C. Martins 
,
Jordana Benfica ,
Germán Peréz-Sanchéz ,
Seishi Shimizu ,
Tânia E. Sintra ,
Nicolas Schaeffer ,
João A. P. Coutinho
,
Jordana Benfica ,
Germán Peréz-Sanchéz ,
Seishi Shimizu ,
Tânia E. Sintra ,
Nicolas Schaeffer ,
João A. P. Coutinho
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Abstract
Hydrotrope pre-aggregation in the presence of inorganic salts is detrimental to the hydrotropic effect. Hydrotropic solubilization is determined by hydrotrope and solute aggregation and driven mainly by hydrophobic interactions.