Published in
Royal Society of Chemistry, Dalton Transactions, 42(51), p. 16070-16081, 2022
DOI: 10.1039/d2dt02079c
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Kinetics and mechanism of sequential ring methyl C–H activation in cyclopentadienyl rhodium(iii) complexes
Journal article published in 2022 by
Alexandra Sink 
,
Samya Banerjee ,
Juliusz A. Wolny ,
Cinzia Imberti ,
Edward C. Lant ,
Marc Walker ,
Volker Schünemann ,
Peter J. Sadler
,
Samya Banerjee ,
Juliusz A. Wolny ,
Cinzia Imberti ,
Edward C. Lant ,
Marc Walker ,
Volker Schünemann ,
Peter J. Sadler
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Abstract
The roles of hydrolysis, concerted proton transfer, and methanol in ring methyl C–H activation via a Rh(i)–fulvene intermediate are elucidated.