Published in
Royal Society of Chemistry, CrystEngComm, 38(24), p. 6628-6641, 2022
DOI: 10.1039/d2ce00867j
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Lanthanide(iii)-oxamato complexes containing Nd<sup>3+</sup> and Ho<sup>3+</sup>: crystal structures, magnetic properties, and ab initio calculations
Journal article published in 2022 by
Raphael C. A. Vaz 
,
Isabela O. Esteves ,
Willian X. C. Oliveira ,
João Honorato ,
Felipe T. Martins ,
Eufrânio N. da Silva Júnior ,
Daniel de C. A. Valente ,
Thiago M. Cardozo ,
Bruno A. C. Horta ,
Davor L. Mariano ,
Wallace C. Nunes ,
Emerson F. Pedroso ,
Cynthia L. M. Pereira
,
Isabela O. Esteves ,
Willian X. C. Oliveira ,
João Honorato ,
Felipe T. Martins ,
Eufrânio N. da Silva Júnior ,
Daniel de C. A. Valente ,
Thiago M. Cardozo ,
Bruno A. C. Horta ,
Davor L. Mariano ,
Wallace C. Nunes ,
Emerson F. Pedroso ,
Cynthia L. M. Pereira
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Abstract
Two series of chlorine or fluorine derivatives containing monooxamato ligands result in diamagnetic complexes of Y3+ and La3+ and paramagnetic complexes of Nd3+ and Ho3+ that behave as single-ion magnets at lower temperatures.