Published in
Royal Society of Chemistry, Organic Chemistry Frontiers, 21(9), p. 5969-5975, 2022
DOI: 10.1039/d2qo01271e
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Palladium-catalyzed regiodivergent arylamination/aryloxygenation of allenamide
Journal article published in 2022 by
Yi Yang,
Hui Wang,
Zehua Sun,
Xinjin Li 
,
Fenggang Sun ,
Qing Liu,
Lizhi Zhang,
Liping Xu ,
Hui Liu
,
Fenggang Sun ,
Qing Liu,
Lizhi Zhang,
Liping Xu ,
Hui Liu
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Abstract
In regiodivergent arylamination/aryloxygenation of allenamides, use of Cy2NMe caused 2,1-arylamination and the corresponding alkenes were formed with excellent Z configuration. Whereas, utilizing Ag2CO3 caused 2,3-aryloxygenation via an unexpected CO2 insertion from Ag2CO3.