Published in
Royal Society of Chemistry, CrystEngComm, 43(24), p. 7554-7562, 2022
DOI: 10.1039/d2ce01161a
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Structural cutting and recombining in layered sodium dysprosium phosphonate: key roles of flexible pyrazinyl hydrazone molecular tools
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Abstract
A cutting [Na5Dy6] phosphonate cluster and a recombinant [Na4Dy8]∞ phosphonate layer are isolated using the pyrazinyl hydrazone ligand. The latter presents the first heterometal phosphonate exhibiting triple N-bridges of pyrazinyl groups.