Published in
Royal Society of Chemistry, CrystEngComm, 42(24), p. 7465-7481, 2022
DOI: 10.1039/d2ce00900e
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Spontaneous formation of hierarchical structures in some polylactide/polysilsesquioxane blends
Journal article published in 2022 by
Agata S. Herc 
,
Marta K. Dudek ,
Sławomir Kaźmierski ,
Joanna Bojda ,
Witold Kaczorowski ,
Bartłomiej Januszewicz ,
Anna Kowalewska
,
Marta K. Dudek ,
Sławomir Kaźmierski ,
Joanna Bojda ,
Witold Kaczorowski ,
Bartłomiej Januszewicz ,
Anna Kowalewska
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Abstract
Evaporative crystallization of polylactide was modulated by functionalized ladder polysilsesquioxanes through conformational changes in the polyester backbone. Atypical spherulites spontaneously formed a hierarchical 3D superstructure.