Published in
Royal Society of Chemistry, Dalton Transactions, 43(51), p. 16453-16464, 2022
DOI: 10.1039/d2dt02665a
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Inherently chiral helicene-substituted thioalkyl porphyrazine complexes: synthesis and electronic and chiroptical properties
Journal article published in 2022 by
Sandra Belviso 
,
Giulia Marsico ,
Roberta Franzini ,
Claudio Villani ,
Sergio Abbate ,
Giovanna Longhi
,
Giulia Marsico ,
Roberta Franzini ,
Claudio Villani ,
Sergio Abbate ,
Giovanna Longhi
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Abstract
Chiral helicene-substituted porphyrazine metal complexes display HOMO–LUMO charge-transfer transitions from helicenes to macrocycles, being mono-substituted push–pull systems. The absolute configuration of enantiomers is established by ECD computations.