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Royal Society of Chemistry, Dalton Transactions, 1(42), p. 71-74

DOI: 10.1039/c2dt32262e

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Exchange-coupled oxygen- and sulfur-bridged cyclopentadienyl-manganese(ii) cages

Journal article published in 2013 by Charlene A. Smith, Floriana Tuna, Michael Bodensteiner, Madeleine Helliwell, David Collison, Richard A. Layfield ORCID, F. Tuna M Bodensteiner M Helliwell D Collison R A. Layfield C. A. Smith
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The trimetallic complex [{CpMn(μ-OSiPh(3))(2)}(2)Mn] () and the heterocubane [CpMn(μ(3)-SSiPh(3))](4) () are formed by deprotonation of Ph(3)SiQH (Q = O, S) by manganocene, or by transmetallation of manganocene by Ph(3)SiQLi. The Mn(ii) centres in and are antiferromagnetically coupled, with J = -4.4 and -3.0 cm(-1) in and , respectively (-2J formalism).