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Royal Society of Chemistry, Dalton Transactions, 43(51), p. 16557-16564, 2022

DOI: 10.1039/d2dt02274e

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Non-redox reactivity of V(ii) and Fe(ii) formamidinates towards CO<sub>2</sub> resulting in the formation of novel M(ii) carbamates

Journal article published in 2022 by Krzesimir Korona ORCID, Arkadiusz Kornowicz ORCID, Iwona Justyniak ORCID, Michał Terlecki ORCID, Artur Błachowski ORCID, Janusz Lewiński ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Multiple CO2 insertions into the M–N bonds of V(ii) and Fe(ii) bis(formamidinates) led to the isolation of three novel carbamates. The CO2 insertion effectivity depended on the solvent used and the metal centre's coordination sphere geometry.