Published in

Royal Society of Chemistry, Dalton Transactions, 46(51), p. 17664-17670, 2022

DOI: 10.1039/d2dt02950b

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Bulky ligands protect molecular ruby from oxygen quenching

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Steric protection strongly reduces phosphorescence quenching of excited molecular rubies by oxygen. The most bulky ligand enables photoluminescence quantum yields up to 5.1% and lifetimes up to 518 µs in air-saturated acetonitrile.