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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 46(24), p. 28540-28547, 2022

DOI: 10.1039/d2cp04688a

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Charge and adsorption height dependence of the self-metalation of porphyrins on ultrathin MgO(001) films

Journal article published in 2022 by Francesco Presel ORCID, Christian S. Kern, Thomas G. Boné, Florian Schwarz, Peter Puschnig ORCID, Michael G. Ramsey, Martin Sterrer ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

While the self-metalation of 2H-TPP on MgO(001) thin films is mediated by charge transfer, 2H-P self-metalates irrespective of its charge state. The different reactivity is explained based on the molecule-substrate distance.