Published in
Royal Society of Chemistry, Dalton Transactions, 1(52), p. 90-96, 2023
DOI: 10.1039/d2dt02955c
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Metal-directed self-assembly of constitutionally dynamic systems: control of the nuclearity of Pd(ii)/Pt(ii) metallacycles
Journal article published in 2023 by
Iago Neira 
,
Olaya Domarco,
Tamara Rama,
Victor Blanco ,
Carlos Peinador ,
Marcos D. García ,
José M. Quintela
,
Olaya Domarco,
Tamara Rama,
Victor Blanco ,
Carlos Peinador ,
Marcos D. García ,
José M. Quintela
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Abstract
4,4′-Bipyridinium-based ditopic ligands assemble with Pd(ii) centers generating constitutionally dynamic systems in which concentration is a suitable stimulus to influence the speciation between mononuclear [PdL]5+ and dinuclear [Pd2L2]10+ species.