Published in
Royal Society of Chemistry, Physical Chemistry Chemical Physics, 32(25), p. 21708-21722, 2023
DOI: 10.1039/d3cp00745f
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Incorporating ion-specific van der Waals and soft repulsive interactions in the Poisson–Boltzmann theory of electrical double layers
Journal article published in 2023 by
Aniruddha Seal 
,
Utkarsh Tiwari,
Ankur Gupta ,
Ananth Govind Rajan
,
Utkarsh Tiwari,
Ankur Gupta ,
Ananth Govind Rajan
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Abstract
Inclusion of ion-specific Lennard–Jones interactions into the Poisson–Boltzmann theory of electric double layers captures the formation of a Stern layer and leads to qualitatively correct predictions of the double layer capacitance.