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Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 5(12), p. 2924-2931, 2024

DOI: 10.1039/d3ta05389j

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Self-assembly of Pt(ii)-tetrakis(pentafluorophenyl)porphyrin via F⋯F interaction for efficient cocatalyst-free photocatalytic hydrogen evolution

Journal article published in 2024 by Govardhana Babu Bodedla ORCID, Venkatesh Piradi, Waygen Thor ORCID, Ka-Leung Wong ORCID, Xunjin Zhu ORCID, Wai-Yeung Wong ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Self-assembled PtPFTPP via dominant F⋯F interaction restricts aggregation caused quenching (ACQ) in the solid state. This leads to longer-lived photoexcited triplet and thereby higher photocatalytic hydrogen evolution rate of 400 μmol g−1 h−1 compared to self-assembled PtTPP with noticeable ACQ.