Published in
Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 37(10), p. 19618-19625, 2022
DOI: 10.1039/d2ta02245a
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Alloying Sb into all inorganic lead-free CsBi<sub>3</sub>I<sub>10</sub> for improving the crystal growth and photovoltaic performance
Journal article published in 2022 by
Jian Kang,
Shan Chen 
,
Mengmeng Hao,
Junxian Liu ,
Mohammad Al-Mamun ,
Porun Liu ,
Yun Wang ,
Huajie Yin ,
Huijun Zhao
,
Mengmeng Hao,
Junxian Liu ,
Mohammad Al-Mamun ,
Porun Liu ,
Yun Wang ,
Huajie Yin ,
Huijun Zhao
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Abstract
The incorporation of isovalent Sb3+ into all inorganic lead-free CsBi3I10 leads to the improved crystal growth and reduced bandgaps. Solar cells based on Cs(Bi0.7Sb0.3)3I10 yield a champion PCE of 1.54% with a high Voc of 0.81 V.